Nickel-catalyzed Csp2-OMe functionalization for chemoselective aromatic homologation en route to nanographenes
A Ni-catalyzed Csp2−OMe ortho-functionalization methodology to form chemoselectively alkyne monoannulation or aromatic homologation products is reported as a novel protocol towards the valorisation of substrates containing Csp2−OMe units. Double activation of Csp2−OMe and Csp2−F bonds is also demons...
| Authors: | , , , |
|---|---|
| Format: | article |
| Status: | Published version |
| Publication Date: | 2022 |
| Country: | España |
| Institution: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repository: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:10256/20853 |
| Online Access: | http://hdl.handle.net/10256/20853 |
| Access Level: | Open access |
| Keyword: | Catàlisi Catalysis Activació (Química) Activation (Chemistry) Alquins Alkynes Reaccions químiques regioselectives Regioselective chemical reactions |
| Summary: | A Ni-catalyzed Csp2−OMe ortho-functionalization methodology to form chemoselectively alkyne monoannulation or aromatic homologation products is reported as a novel protocol towards the valorisation of substrates containing Csp2−OMe units. Double activation of Csp2−OMe and Csp2−F bonds is also demonstrated. Further use of aromatic homologation products towards the synthesis of nanographene-like compounds is described |
|---|