A reversible phase transition of 2D coordination layers by B-H···Cu(II) interactions in a coordination polymer
Materials that combine flexibility and open metal sites are crucial for myriad applications. In this article, we report a 2D coordination polymer (CP) assembled from CuII ions and a flexible meta-carborane-based linker [Cu(L1)(Solv)]•xSolv (1-DMA, 1-DMF, and 1-MeOH; L1: 1,7-di(4-carboxyphenyl)-1,7-d...
| Autores: | , , , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Universitat Autònoma de Barcelona |
| Repositorio: | Dipòsit Digital de Documents de la UAB |
| Idioma: | inglés |
| OAI Identifier: | oai:ddd.uab.cat:216632 |
| Acceso en línea: | https://ddd.uab.cat/record/216632 https://dx.doi.org/urn:doi:10.3390/molecules24173204 |
| Access Level: | acceso abierto |
| Palabra clave: | Metal-organic frameworks Open metal sites Boron hydrides Carborane Reversible phase transition |
| id |
ES_b3acf00a8880e35751e7e594df38dd4d |
|---|---|
| oai_identifier_str |
oai:ddd.uab.cat:216632 |
| network_acronym_str |
ES |
| network_name_str |
España |
| spelling |
A reversible phase transition of 2D coordination layers by B-H···Cu(II) interactions in a coordination polymer Gan, Lei|||0000-0002-4230-3662 Fonquernie, Pol G. Light, Mark E.|||0000-0002-0585-0843 Norjmaa, Gantulga|||0000-0001-5209-895X Ujaque, Gregori|||0000-0001-5896-9998 Choquesillo-Lazarte, Duane|||0000-0002-7077-8972 Fraile, Julio|||0000-0003-2961-7920 Teixidor, Francesc|||0000-0002-3010-2417 Viñas, Clara|||0000-0001-5000-0277 Giner Planas, José|||0000-0002-1648-2169 Metal-organic frameworks Open metal sites Boron hydrides Carborane Reversible phase transition Materials that combine flexibility and open metal sites are crucial for myriad applications. In this article, we report a 2D coordination polymer (CP) assembled from CuII ions and a flexible meta-carborane-based linker [Cu(L1)(Solv)]•xSolv (1-DMA, 1-DMF, and 1-MeOH; L1: 1,7-di(4-carboxyphenyl)-1,7-dicarba-closo-dodecaborane). 1-DMF undergoes an unusual example of reversible phase transition on solvent treatment (i.e., MeOH and CHCl). Solvent exchange, followed by thermal activation provided a new porous phase that exhibits an estimated Brunauer-Emmett-Teller (BET) surface area of 301 m g and is capable of a CO uptake of 41 cm g. The transformation is reversible and 1-DMF is reformed on addition of DMF to the porous phase. We provide evidence for the reversible process being the result of the formation/cleavage of weak but attractive B-H···Cu interactions by a combination of single-crystal (SCXRD), powder (PXRD) X-ray diffraction, Raman spectroscopy, and DFT calculations. https://ddd.uab.cat/record/216632 https://dx.doi.org/urn:doi:10.3390/molecules24173204 |
| title |
A reversible phase transition of 2D coordination layers by B-H···Cu(II) interactions in a coordination polymer |
| spellingShingle |
A reversible phase transition of 2D coordination layers by B-H···Cu(II) interactions in a coordination polymer Gan, Lei|||0000-0002-4230-3662 Metal-organic frameworks Open metal sites Boron hydrides Carborane Reversible phase transition |
| title_short |
A reversible phase transition of 2D coordination layers by B-H···Cu(II) interactions in a coordination polymer |
| title_full |
A reversible phase transition of 2D coordination layers by B-H···Cu(II) interactions in a coordination polymer |
| title_fullStr |
A reversible phase transition of 2D coordination layers by B-H···Cu(II) interactions in a coordination polymer |
| title_full_unstemmed |
A reversible phase transition of 2D coordination layers by B-H···Cu(II) interactions in a coordination polymer |
| title_sort |
A reversible phase transition of 2D coordination layers by B-H···Cu(II) interactions in a coordination polymer |
| author |
Gan, Lei|||0000-0002-4230-3662 |
| author_facet |
Gan, Lei|||0000-0002-4230-3662 Fonquernie, Pol G. Light, Mark E.|||0000-0002-0585-0843 Norjmaa, Gantulga|||0000-0001-5209-895X Ujaque, Gregori|||0000-0001-5896-9998 Choquesillo-Lazarte, Duane|||0000-0002-7077-8972 Fraile, Julio|||0000-0003-2961-7920 Teixidor, Francesc|||0000-0002-3010-2417 Viñas, Clara|||0000-0001-5000-0277 Giner Planas, José|||0000-0002-1648-2169 |
| author_role |
author |
| author2 |
Fonquernie, Pol G. Light, Mark E.|||0000-0002-0585-0843 Norjmaa, Gantulga|||0000-0001-5209-895X Ujaque, Gregori|||0000-0001-5896-9998 Choquesillo-Lazarte, Duane|||0000-0002-7077-8972 Fraile, Julio|||0000-0003-2961-7920 Teixidor, Francesc|||0000-0002-3010-2417 Viñas, Clara|||0000-0001-5000-0277 Giner Planas, José|||0000-0002-1648-2169 |
| author2_role |
author author author author author author author author author |
| topic |
Metal-organic frameworks Open metal sites Boron hydrides Carborane Reversible phase transition |
| topic_facet |
Metal-organic frameworks Open metal sites Boron hydrides Carborane Reversible phase transition |
| description |
Materials that combine flexibility and open metal sites are crucial for myriad applications. In this article, we report a 2D coordination polymer (CP) assembled from CuII ions and a flexible meta-carborane-based linker [Cu(L1)(Solv)]•xSolv (1-DMA, 1-DMF, and 1-MeOH; L1: 1,7-di(4-carboxyphenyl)-1,7-dicarba-closo-dodecaborane). 1-DMF undergoes an unusual example of reversible phase transition on solvent treatment (i.e., MeOH and CHCl). Solvent exchange, followed by thermal activation provided a new porous phase that exhibits an estimated Brunauer-Emmett-Teller (BET) surface area of 301 m g and is capable of a CO uptake of 41 cm g. The transformation is reversible and 1-DMF is reformed on addition of DMF to the porous phase. We provide evidence for the reversible process being the result of the formation/cleavage of weak but attractive B-H···Cu interactions by a combination of single-crystal (SCXRD), powder (PXRD) X-ray diffraction, Raman spectroscopy, and DFT calculations. |
| publishDate |
2019 |
| format |
article |
| url |
https://ddd.uab.cat/record/216632 https://dx.doi.org/urn:doi:10.3390/molecules24173204 |
| language |
eng |
| eu_rights_str_mv |
openAccess |
| institution |
Universitat Autònoma de Barcelona |
| collection |
Dipòsit Digital de Documents de la UAB |
| reponame_str |
Dipòsit Digital de Documents de la UAB |
| instname_str |
Universitat Autònoma de Barcelona |
| _version_ |
1878439598962507776 |
| publishDateSort |
2019 |
| author_browse |
Choquesillo-Lazarte, Duane|||0000-0002-7077-8972 Fonquernie, Pol G. Fraile, Julio|||0000-0003-2961-7920 Gan, Lei|||0000-0002-4230-3662 Giner Planas, José|||0000-0002-1648-2169 Light, Mark E.|||0000-0002-0585-0843 Norjmaa, Gantulga|||0000-0001-5209-895X Teixidor, Francesc|||0000-0002-3010-2417 Ujaque, Gregori|||0000-0001-5896-9998 Viñas, Clara|||0000-0001-5000-0277 |
| score |
6,924472 |