Coumarin based light responsive healable waterborne polyurethanes
Waterborne polyurethanes containing coumarin as chain extenders were successfully synthesized. Taking advantage of the photoinduced [2+2] cycloaddition reaction of coumarin moieties, this work evaluated the healing abilities of these materials. The photochemical process was analyzed by UV spectrosco...
| Autores: | , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2016 |
| País: | España |
| Institución: | Universidad del País Vasco |
| Repositorio: | Addi. Archivo Digital para la Docencia y la Investigación |
| OAI Identifier: | oai:addi.ehu.eus:10810/72129 |
| Acceso en línea: | http://hdl.handle.net/10810/72129 |
| Access Level: | acceso abierto |
| Palabra clave: | Coumarin waterborne polyurethanes sunlight light responsive healing |
| id |
ES_f36db42e67a236e089b8a813a6adf29f |
|---|---|
| oai_identifier_str |
oai:addi.ehu.eus:10810/72129 |
| network_acronym_str |
ES |
| network_name_str |
España |
| spelling |
Coumarin based light responsive healable waterborne polyurethanes Aguirresarobe Hernández, Robert Martin, Loli Aramburu Ocáriz, Nora Irusta Maritxalar, María Lourdes Fernández Berridi, María José Coumarin waterborne polyurethanes sunlight light responsive healing Waterborne polyurethanes containing coumarin as chain extenders were successfully synthesized. Taking advantage of the photoinduced [2+2] cycloaddition reaction of coumarin moieties, this work evaluated the healing abilities of these materials. The photochemical process was analyzed by UV spectroscopy and the cycloaddition reaction kinetics was studied. In addition, the healing abilities of the synthesized waterborne polyurethanes were determined by means of scratch refilling studies and strain-stress tests. The irradiation conditions as well as the polymeric chain mobility on the fracture and the capacity to generate polymer networks by coumarin linkages were demonstrated to be the main factors affecting the healing process. The behavior of these systems was also determined under the direct irradiation of sunlight. The authors acknowledge the University of the Basque Country UPV/EHU (UFI 11/56), the Basque Government (Ayuda a grupos de investigación del sistema universitario vasco IT 618/13 and PhD scholarship) and the Ministerio de Economía y Competitividad (CTQ2013-4113-R) for the funding received to develop this work. Technical and Human support provided by Macrobehavior-Mesostructure-Nanotechnology and NMR SGiker service of UPV/EHU is also gratefully acknowledged. Elsevier http://hdl.handle.net/10810/72129 |
| title |
Coumarin based light responsive healable waterborne polyurethanes |
| spellingShingle |
Coumarin based light responsive healable waterborne polyurethanes Aguirresarobe Hernández, Robert Coumarin waterborne polyurethanes sunlight light responsive healing |
| title_short |
Coumarin based light responsive healable waterborne polyurethanes |
| title_full |
Coumarin based light responsive healable waterborne polyurethanes |
| title_fullStr |
Coumarin based light responsive healable waterborne polyurethanes |
| title_full_unstemmed |
Coumarin based light responsive healable waterborne polyurethanes |
| title_sort |
Coumarin based light responsive healable waterborne polyurethanes |
| author |
Aguirresarobe Hernández, Robert |
| author_facet |
Aguirresarobe Hernández, Robert Martin, Loli Aramburu Ocáriz, Nora Irusta Maritxalar, María Lourdes Fernández Berridi, María José |
| author_role |
author |
| author2 |
Martin, Loli Aramburu Ocáriz, Nora Irusta Maritxalar, María Lourdes Fernández Berridi, María José |
| author2_role |
author author author author |
| topic |
Coumarin waterborne polyurethanes sunlight light responsive healing |
| topic_facet |
Coumarin waterborne polyurethanes sunlight light responsive healing |
| description |
Waterborne polyurethanes containing coumarin as chain extenders were successfully synthesized. Taking advantage of the photoinduced [2+2] cycloaddition reaction of coumarin moieties, this work evaluated the healing abilities of these materials. The photochemical process was analyzed by UV spectroscopy and the cycloaddition reaction kinetics was studied. In addition, the healing abilities of the synthesized waterborne polyurethanes were determined by means of scratch refilling studies and strain-stress tests. The irradiation conditions as well as the polymeric chain mobility on the fracture and the capacity to generate polymer networks by coumarin linkages were demonstrated to be the main factors affecting the healing process. The behavior of these systems was also determined under the direct irradiation of sunlight. |
| publishDate |
2016 |
| format |
article |
| url |
http://hdl.handle.net/10810/72129 |
| eu_rights_str_mv |
openAccess |
| publisher |
Elsevier |
| institution |
Universidad del País Vasco |
| collection |
Addi. Archivo Digital para la Docencia y la Investigación |
| reponame_str |
Addi. Archivo Digital para la Docencia y la Investigación |
| instname_str |
Universidad del País Vasco |
| _version_ |
1878442898079350784 |
| publishDateSort |
2016 |
| author_browse |
Aguirresarobe Hernández, Robert Aramburu Ocáriz, Nora Fernández Berridi, María José Irusta Maritxalar, María Lourdes Martin, Loli |
| publisherStr |
Elsevier |
| score |
6,924472 |