Recovery of phenolic compounds from wine lees using green processing: Identifying target molecules and assessing membrane ultrafiltration performance
Winery wastes are rich in polyphenols with high added value to be used in cosmetics, pharmaceuticals, and food products. This work aims at recovering and purifying the polyphenolic fraction occurring in the malolactic fermentation lees generated during the production of Albariño wines. Phenolic acid...
| Authors: | , , , , , , , , , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2023 |
| Country: | España |
| Institution: | Universidad de Barcelona |
| Repository: | Dipòsit Digital de la UB |
| OAI Identifier: | oai:diposit.ub.edu:2445/193548 |
| Online Access: | https://hdl.handle.net/2445/193548 |
| Access Level: | Open access |
| Keyword: | Polifenols Ultrafiltració Antioxidants Polyphenols Ultrafiltration |
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oai:diposit.ub.edu:2445/193548 |
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Recovery of phenolic compounds from wine lees using green processing: Identifying target molecules and assessing membrane ultrafiltration performance Mir-Cerdà, Aina Carretero, Iris Coves, José Rubén Pedrouso, Alba Castro-Barros, Celia María Alvarino, Teresa Cortina, José Luis Saurina, Javier Granados i Juan, Mercè Sentellas, Sonia Polifenols Ultrafiltració Antioxidants Polyphenols Ultrafiltration Winery wastes are rich in polyphenols with high added value to be used in cosmetics, pharmaceuticals, and food products. This work aims at recovering and purifying the polyphenolic fraction occurring in the malolactic fermentation lees generated during the production of Albariño wines. Phenolic acids, flavonoids, and related compounds were recovered from this oenological waste by green liquid extraction using water as the solvent. The resulting extract solution was microfiltered to remove microparticles and further treated by ultrafiltration (UF) using membranes of 30 kDa and 5 kDa molecular weight cut-offs (MWCOs). The feed sample and the filtrate and retentate solutions from each membrane system were analyzed by reversed-phase liquid chromatography (HPLC) with UV and mass spectrometric (MS) detection. The most abundant polyphenols in the extracts were identified and quantified, namely: caftaric acid with a concentration of 200 µg g−1 and trans-coutaric acid, cis-coutaric acid, gallic acid, and astilbin with concentrations between 15 and 40 µg g−1. Other minor phenolic acids and flavanols were also found. The UF process using the 30 kDa membrane did not modify the extract composition, but filtration through the 5 kDa poly-acrylonitrile membrane elicited a decrease in polyphenolic content. Hence, the 30 kDa membrane was recommended to further pre-process the extracts. The combined extraction and purification process presented here is environmentally friendly and demonstrates that malolactic fermentation lees of Albariño wines are a valuable source of phenolic compounds, especially phenolic acids. Elsevier B.V. https://hdl.handle.net/2445/193548 |
| title |
Recovery of phenolic compounds from wine lees using green processing: Identifying target molecules and assessing membrane ultrafiltration performance |
| spellingShingle |
Recovery of phenolic compounds from wine lees using green processing: Identifying target molecules and assessing membrane ultrafiltration performance Mir-Cerdà, Aina Polifenols Ultrafiltració Antioxidants Polyphenols Ultrafiltration |
| title_short |
Recovery of phenolic compounds from wine lees using green processing: Identifying target molecules and assessing membrane ultrafiltration performance |
| title_full |
Recovery of phenolic compounds from wine lees using green processing: Identifying target molecules and assessing membrane ultrafiltration performance |
| title_fullStr |
Recovery of phenolic compounds from wine lees using green processing: Identifying target molecules and assessing membrane ultrafiltration performance |
| title_full_unstemmed |
Recovery of phenolic compounds from wine lees using green processing: Identifying target molecules and assessing membrane ultrafiltration performance |
| title_sort |
Recovery of phenolic compounds from wine lees using green processing: Identifying target molecules and assessing membrane ultrafiltration performance |
| author |
Mir-Cerdà, Aina |
| author_facet |
Mir-Cerdà, Aina Carretero, Iris Coves, José Rubén Pedrouso, Alba Castro-Barros, Celia María Alvarino, Teresa Cortina, José Luis Saurina, Javier Granados i Juan, Mercè Sentellas, Sonia |
| author_role |
author |
| author2 |
Carretero, Iris Coves, José Rubén Pedrouso, Alba Castro-Barros, Celia María Alvarino, Teresa Cortina, José Luis Saurina, Javier Granados i Juan, Mercè Sentellas, Sonia |
| author2_role |
author author author author author author author author author |
| topic |
Polifenols Ultrafiltració Antioxidants Polyphenols Ultrafiltration |
| topic_facet |
Polifenols Ultrafiltració Antioxidants Polyphenols Ultrafiltration |
| description |
Winery wastes are rich in polyphenols with high added value to be used in cosmetics, pharmaceuticals, and food products. This work aims at recovering and purifying the polyphenolic fraction occurring in the malolactic fermentation lees generated during the production of Albariño wines. Phenolic acids, flavonoids, and related compounds were recovered from this oenological waste by green liquid extraction using water as the solvent. The resulting extract solution was microfiltered to remove microparticles and further treated by ultrafiltration (UF) using membranes of 30 kDa and 5 kDa molecular weight cut-offs (MWCOs). The feed sample and the filtrate and retentate solutions from each membrane system were analyzed by reversed-phase liquid chromatography (HPLC) with UV and mass spectrometric (MS) detection. The most abundant polyphenols in the extracts were identified and quantified, namely: caftaric acid with a concentration of 200 µg g−1 and trans-coutaric acid, cis-coutaric acid, gallic acid, and astilbin with concentrations between 15 and 40 µg g−1. Other minor phenolic acids and flavanols were also found. The UF process using the 30 kDa membrane did not modify the extract composition, but filtration through the 5 kDa poly-acrylonitrile membrane elicited a decrease in polyphenolic content. Hence, the 30 kDa membrane was recommended to further pre-process the extracts. The combined extraction and purification process presented here is environmentally friendly and demonstrates that malolactic fermentation lees of Albariño wines are a valuable source of phenolic compounds, especially phenolic acids. |
| publishDate |
2023 |
| format |
article |
| status_str |
publishedVersion |
| url |
https://hdl.handle.net/2445/193548 |
| eu_rights_str_mv |
openAccess |
| publisher |
Elsevier B.V. |
| institution |
Universidad de Barcelona |
| collection |
Dipòsit Digital de la UB |
| reponame_str |
Dipòsit Digital de la UB |
| instname_str |
Universidad de Barcelona |
| _version_ |
1878443162268073985 |
| publishDateSort |
2023 |
| author_browse |
Alvarino, Teresa Carretero, Iris Castro-Barros, Celia María Cortina, José Luis Coves, José Rubén Granados i Juan, Mercè Mir-Cerdà, Aina Pedrouso, Alba Saurina, Javier Sentellas, Sonia |
| publisherStr |
Elsevier B.V. |
| score |
6,924472 |